paper

Dynamic Modeling and Control of Multi-Stack Alkaline Water Electrolysis Systems with Shared Gas Separators and Lye Circulation:Industrial Data-Based Validation and Simulation

arXiv:2501.14576

Abstract

An emerging approach for large-scale renewable hydrogen production is integrating multiple alkaline water electrolysis (AWE) stacks into one balance-of-plant (BoP) system, sharing gas-lye separation and lye circulation components. While this configuration, termed -in-1, reduces cost and complexity, its dynamic performance under fluctuating power remains unclear compared with conventional 1-in-1 systems. This paper develops a state-space model of the multi-stack AWE system, capturing lye circulation, temperature, and hydrogen-to-oxygen (HTO) dynamics, calibrated via experiments on a 4,000 Nm/h-rated 4-in-1 system. A mixed-integer quadratic programming (MIQP)-based predictive controller is then designed to coordinate inter-stack current distribution, lye flow, and cooling for load tracking and operational stability. Simulations on the experimentally validated model show that a -in-1 system achieves similar performance compared to four parallel 1-in-1 systems under continuous operation. Differences in load-tracking, temperature stabilization errors, and specific energy consumption remain below 0.015 MW, 0.346 K, and 0.001 kWh/Nm under wind power supply when all stacks remain online.