Superconductivity modulated by structural phase transitions in pressurized vanadium-based kagome metals

Abstract

The interplay of superconductivity with electronic and structural instabilities on the kagome lattice provides a fertile ground for the emergence of unusual phenomena. The vanadium-based kagome metals $A$V${}_3$Sb${}_5$ ($A=$ K, Rb, Cs) exhibit superconductivity on an almost ideal kagome lattice, with the superconducting transition temperature $T_{\mathrm{c}}$ forming two domes upon pressure-tuning. The first dome arises from the competition between superconductivity and a charge-density-wave, whereas the origin for the second dome remains unclear. Herein, we show that the appearance of the second superconducting dome in KV${}_3$Sb${}_5$ and RbV${}_3$Sb${}_5$ is associated with transitions from hexagonal $P6$/$mmm$ to monoclinic $P2$/$m$ structures, evidenced by splitting of structural peaks from synchrotron powder X-ray diffraction experiments and imaginary phonon frequencies in first-principles calculations. In KV${}_3$Sb${}_5$, transition to an orthorhombic $Pmmm$ structure is further observed for pressure $p\gtrsim 20$ GPa, and is correlated with the strong suppression of $T_{\mathrm{c}}$ in the second superconducting dome. Our findings indicate distortions of the crystal structure modulates superconductivity in $A$V${}_3$Sb${}_5$ under pressure, providing a platform to study the emergence of superconductivity in the presence of multiple structural instabilities.