Evidence of s-wave superconductivity in the noncentrosymmetric La${}_7$Ir${}_3$

Abstract

Superconductivity in noncentrosymmetric compounds has attracted sustained interest in the last decades. Here we present a detailed study on the transport, thermodynamic properties and the band structure of the noncentrosymmetric superconductor La${}_7$Ir${}_3$ ($T_c$ $\sim$2.3 K) that was recently proposed to break the time-reversal symmetry. It is found that La${}_7$Ir${}_3$ displays a moderately large electronic heat capacity (Sommerfeld coefficient ${\hat{I}}_n^3$ $\sim$ 53.1 mJ/mol ${\text{K}}^2$) and a significantly enhanced Kadowaki-Woods ratio (KWR $\sim$ 32 $\hat{I}¼\hat{I}\text{c◯}$ cm mol${}^2$ K${}^2$ J${}^{-2}$) that is greater than the typical value ($\sim$ 10 $\hat{I}¼\hat{I}\text{c◯}$ cm mol${}^2$ K${}^2$ J${}^{-2}$) for strongly correlated electron systems. The upper critical field $H_{c2}$ was seen to be nicely described by the single-band Werthamer-Helfand-Hohenberg model down to very low temperatures. The hydrostatic pressure effects on the superconductivity were also investigated. The heat capacity below $T_c$ reveals a dominant s-wave gap with the magnitude close to the BCS value. The first-principles calculations yield the electron-phonon coupling constant $\hat{I}»$ = 0.81 and the logarithmically averaged frequency $\ddot{I}{‰}_{ln}$ = 78.5 K, resulting in a theoretical $T_c$ = 2.5 K, close to the experimental value. Our calculations suggest that the enhanced electronic heat capacity is more likely due to electron-phonon coupling, rather than the electron-electron correlation effects. Collectively, these results place severe constraints on any theory of exotic superconductivity in this system.