Revealing the Coulomb interaction strength in a cuprate superconductor

Abstract

We study optimally doped Bi${}_2$Sr${}_2$Ca${}_{0.92}$Y${}_{0.08}$Cu${}_2$O${}_{8+\hat{I}´}$ (Bi2212) using angle-resolved two-photon photoemission spectroscopy. Three spectral features are resolved near 1.5, 2.7, and 3.6 eV above the Fermi level. By tuning the photon energy, we determine that the 2.7-eV feature arises predominantly from unoccupied states. The 1.5- and 3.6-eV features reflect unoccupied states whose spectral intensities are strongly modulated by the corresponding occupied states. These unoccupied states are consistent with the prediction from a cluster perturbation theory based on the single-band Hubbard model. Through this comparison, a Coulomb interaction strength U of 2.7 eV is extracted. Our study complements equilibrium photoemission spectroscopy and provides a direct spectroscopic measurement of the unoccupied states in cuprates. The determined Coulomb U indicates that the charge-transfer gap of optimally doped Bi2212 is 1.1 eV.